NEED & USE OF DRINKING WATER
- 1974 → The water Act (Prevention & Control of pollution) 
- 1981 → The air Act (Prevention & Control of pollution) 
- 1986 → The environment protection Act 
- 1987 → 1st National water policy by govt of india 
- % of water in earth = 71% = 35 x 10¹²m³, Fresh water = 2% 
- Sea water = 80% of oxygen contain in freshwater stream 
- DBU → Designated best uses 
- OSHO → Occupational safety and health administration 
- Intakes → Device installed for draining water from source 
- Fresh water → Alkaline (pH > 7) 
- Septic tank → Acidic (pH < 7) 
- Fire extinguisher → Type extinguishers, Foam type extinguishers, dry chemical powder extinguishers, mist type, wet chemical type, CO2 type extinguishers 
- Keystone species → Which if eliminated seriously affect the ecosystem 
- Whole some water → Not chemically pure but doesn't contain anything harmful to human health 
- Population response → An interdependent population of organism interacting with their physical and chemical environment 
- Fire hydrants are usually fitted in the water mains about 100 - 150 m Apart 
- Losses in water supply → Assumed as 15% 
- Water from springs are free from impurities 
- Most important source of water for public water supplies rivers 
- Time gap between explosion and machine process within which the ventilation system is called should clear all poison gases and dust in tunnels = 30min 
Population forecasting
- Methods → Arithmetic increase method, geometric increase method, method of wearing increment, decreasing rate of growth method, simple graphical method, comparative graphical method, master plan method or joining method, Logistic Curve method 
- Population depends on → Birth & death rates, migration 
- Best judged by → Geometric increase method 
Arithmetic increase method
- Old , Very large cities, constant rate of change of population 
- Pn=Po+nx̅ 
- n = decades 
Geometric increase Method/Uniform ↑es method
- GOI recommended 
- New cities expanding with faster rate 
- Gives highest value of forecasted 
- % increases in population from decade to decade remains constant 
- Pn =Po(1+r/100)n→ ↑es given per decade 
- Pn = Po ern→ ↑es given per year 
- r=r /n=(r1+r2+r3)1/n 
incremental ↑es method or Method of varying increment
- Any city old or new 
- Pn=Po+nx̅+n(n+1)y̅ /2 
- y̅ → avg of increment increase of known decades 
S-shaped/logistic/Growth curve
- Population vs time 
- By PF verhulst 
- For community with limited land area for future 
Water Demand (IS 1172-1963) → Per person per day
- Annual average daily requirement per person per day 
- IS 1172-1963 → Total requirement of water 
- Small town or Avg domestic purpose = 135 → Drinking = 5, cooking = 5, Bathing = 55, cloth washing = 20, Utensils washing = 10, House washing = 10, Flushing of a water closet = 30 
- indian cities = 200 → Water supply + Drainage + Sanitation 
- Domestic + commercial + industrial for avg indian people or LIG = 270 lpcd & HIG = 335 lpcd 
- Population > 10 lac = 335 - 360 ltr 
- Population < 1 lac = 275 - 335 ltr 
- Hospital → Bed ≤ 100 = 340, Bed > 100 = 450 lpcd 
- Office = 45 - 90 lpcd 
- School/college → Day = 45, Residential = 135 
- Automobile vehicle = 40 lpcd 
- Paper mfd unit consume max water 
Peak Q for domestic purposes per capita per minute
- 5 - 10 user = 1.80 ltr 
- 15 users = 1.20 ltr 
- 20 users = 1.35 ltr 
Fire Demand → BNKF
- Q=100P → Q = kiloliters 
1.Buston's
- Q=5663P → Q = litre/min, P = Thousands 
2.National Board of fire underWriters
- Q=4637P (1-0.01P) → P ≤ 2 lakhs, Q = litre/min, P = Thousands 
3.Kuichling formula
- Q=3182P → Most preferred, Q = litre/min, P = Thousands 
4.Freeman's Formula:
- Q=1136(P/5 + 10) → Q = litre/min, P = Thousands 
Factor affecting per capita Demand
- City size, Climatic conditions, Habit of people 
- Quality of water → ↑es demand 
- Developed of sewerage system → ↑es demand 
- Pressure in distⁿ system↑es → ↑es demand 
- Cost of water → ↓es demand 
Normal variation
- Max hourly demand for peak demand = 2.7 x Annual hourly consumption of the max day 
- Max hourly demand = 1.5 x max daily demand 
- Max daily demand(MDD) = 1.8 x Annual Average daily demand 
- 1.5 x 1.8 = 2.7 
- Max weekly demand = 1.48 x Annual Average daily demand 
- Max monthly demand = 1.28 x Annual Average daily demand 
Daily variation factor
- Population < 50k = 1.5 
- 50k - 100k = 2.5 → Medium town 
- Population > 100k = 3.5 
Coincident Draft
- CD = Max of {max daily demand + fire demand & Max hourly demand (MHD)} 
Design Parameter & period
- Average water demand of a small town in India is estimated on the basis of domestic use only 
i. Water treatment, Service/storage reservoir (overhead or ground level), Intake, main pipe line
- t = 15 yrs 
- MDD 
ii. Distⁿ system, pipe connection to several treatment unit, water supply scheme
- t = 30 yrs 
- MHD on max day or Coincident Draft (whichever is more) 
- For a town water supply scheme is commonly design for a population after three decades 
iii. Sewage treatment units
- T = 25 years 
- For Avg flow 
vi. Pumps
- for 2 x Annual average daily demand 
WATER QUALITY
- Acidity → Due to presence of carbon dioxide in water, 
- Carbon monoxide (CO) act as Asphyxiant 
- Acid fermentation → Leads to the formation of volatile fatty acids 
- Most important water quality parameter for domestic use of water is coliform group of organisms 
- Suspended impurities in water → Bacteria, algae, silt 
- Dissolved impurities → iron, 
- Colloidal impurities → Finally divided Dispersion of solid particle in water which are not visible to the naked eye and cannot be removed by ordinary filters 
- Benthos → Organisms attached or resting at the bottom or living in the bottom sediments In freshwater 
- Disappearance of pink colour of water from a well due to addition of KMnO4 indicates → Water contained organic matter 
Permissible & Rejection limit
- IS 10500 : 2012 → Drinking water specification 
- Rejection Limit → Permissible limit in absence of an alternative source → Ex. Permissible limits in Absence of alternative sources for Hardness & Chloride are 600 & 1000 ppm respectively 
- Aluminium and Boron have some relaxation in acceptable limit in the absence of the Alternative sources 
- 1ppm = 1mg/L → 1g/L = 1000 ppm 
inland surface water(IS 2490-1981)
- Suspended solids are limited to 100 mg/L 
- pH = 5.5 - 9.0 
A. Physical Water Quality Parameter: (T³CS.)*
i. Suspended solids :
- Only surface water not underground 
- Dissolved solid is chemical parameters 
ii. Turbidity
- Measure of the amount to which light is absorbed or scattered by the suspended material in water 
- Turbidity is mostly due to colloidal particle, Clay + Silt particles, Suspended solid 
- Turbidity is indicator of presence of suspended inorganic matter 
- Turbidity rod → Std. Silica scale(ppm), it is a field method 
- Jackson's turbidity meter: in JTU for T > 25 ppm → Basis of absorption of light 
- Baylis turbidimeter: FTU, absorption, using blue cobalt plate. 
- Nephelometer → NTU → Scattering principle 
- 1 NTU → 1 mg of formazine dissolved in 1 litre of distilled water with the test being run according to scattering principle 
- B & N Methods are colour matching techniques & used for domestic water supply & are more precise. 
- Turbidity → Running (river) > Still water (Lake) 
- High turbidity encourage after growth of bacteria in distribution system 
iii. Colour
- Due to dissolved impurities 
- Tintometer → Colour matching techniques → Measurement of colours 
- Measured on Platinum Cobalt scale 
- 1TCU = 1 mg/L → Platinum in form of chloroplatinate ion 
- True colour unit (Hazen unit) 
iv. Taste & Odour
- Due to Dissolve gases 
- Osmoscope → Graduated with pO value = (0 - 5) 
- Very strong > strong > distinct > faint > very faint > No perceptible odour 
- Removed by → Aeration, Coagulation, Activated carbon → Oxidation is best method to control taste & odour 
- Threshold order No. → TON = (A+B)/A = diluted solⁿ/undiluted(distilled water) 
- Flavour threshold No. → FTN = Taste free water required/Water to dilute 
- Sulphur → Rotten eggs 
- Type of Odour characteristics → Degree of sweetness, Degree of pungency, Degree of smokiness 
v. Temperature
- ideal = 13°C 
- ↑es 10°C → Biological activity is doubled 
B. Chemical Properties
i. TDS: Total dissolved Solids
- By evaporating sample of water 
- TDS (ppm) = 0.65 x EC(μMHo/cm) 
- Total solid = TDS + Suspended solid 
- Electrical conductivity of water increases with total dissolved solids 
2. Alkalinity
- Due to Ca++ 
- Quantity of ions in water that will react to neutralise hydrogen ions(H+ ion) or Acid. 
- Due to Carbonate (CO3⁻²), Bicarbonate (HCO3⁻) & Caustic (OH⁻). 
- Titration → Express in terms of ppm a CaCO3 
3. pH
- pH = - log10[H+] → [H+] = moles/litre 
- by Potentiometer 
- Acid indicator → Methyl orange & Basic indicator → Phenolphthalein 
- Acidic water → Corrosion & Alkaline water → incrustation of pipe 
- Acidic Ratio = [H+]1/[H+]2 = Ratio of H+ 
- pH + pOH = 14 → [H+][OH-] = 10⁻¹⁴ 
- H⁻ⁿ → pH = n 
- Talyred → PH indicator that produced yellow as the final colour when added to water sample 
- Sodic soil → pH > 8.5 
- Industrial excellent discharge into inline surface water → pH = 5.5 - 9.0 
4. Hardness
- Due to divalent metallic ions (Calcium and magnesium) 
- Measured by Spectrophotometric techniques 
- NaCl → Softens the water 
- What used in boilers should be relatively soft 
- Groundwater is considered soft (H = 0-60 ppm) 
- For public water supply hard water is not used because it consume more soap 
- Hardness of Boiler feed water < 50 ppm 
Temporary/Carbonate H
- Removed by boiling or adding lime 
- HCO3⁻ & CO3⁻² of calcium & magnesium → Carbonate and bicarbonate of calcium and magnesium 
- No harm to health 
Permanent/Non Carbonate H
- Sulphate(SO4), Chloride & Nitrate of Calcium & magnesium 
- Removed by → Zeolite, lime-soda Process & Deionisation process. 
- Pseudo Hardness → Due to Sodium 
- TH = (Ca²+ mg² + Al²) x 50 → All in millieq/ltr 
- TH =50/20 [Ca²] + 50/12 [Mg²] + 50/9[AL³] → All in mg/Ltr 
- TH, A → mg/L as CaCo3 
- A = 50/61 [HCO3⁻] + 50/30 [CO3⁻²] + 50/17[OH⁻] → All in mg/L as Calcium carbonate (CaCO3) 
- CH = min of [TA & TH] 
- NCH = TH - CH 
- TH > TA → CH = TA 
- TH ≤ TA → CH = TH 
- Water from lake source is likely to be hard 
Method to determine Hardness
i. Dr. Clark's method
- based on that hardness producing substance reacts with soap & forms insoluble compounds before leather is produced 
- Hardness is expressed in degrees 
ii. Hehner's method
- Determine permanent hardness. 
iii. Versenate or EDTA Method
- By titration 
- indicator → EBT (Erio-chrome Black T (Wine red)) → EBT form red Colour & Titration change it to Blue 
- Solution → EDTA (Ethylene Diamine Tetra-acetic Acid) 
5. Chloride Content
- Mohr's method → Concentration of chloride ions, Using Titrant → Silver nitrate(AgNO3) and indicator → Potassium chromate (K2Cr2O7) 
- Normally in the form of sodium chloride 
- excess → Cardiac problem, Kidney disease, Brackish water 
6. Nitrogen Content
- indicates presence of Organic matter 
- a) Free Ammonia →recent pollution 
- b) Organic Ammonia (Albuminoid) → Quantity of Nitrogen before Decomposition has started. 
- c) Nitrite - Partly decomposed condition 
- d) Nitrate - old pollution (fully oxidised) 
- Kjeldahl Nitrogen Ammonia = Free + organic Ammonia 
- Total Kjeldahl Nitrogen = Organic + Ammoniacal Nitrogen 
- Blue baby Disease (Methemoglobinemia) → if Nitrate > 45ppm 
- Blue green Algae can fix atmospheric nitrogen 
7. Fluorides
- Absence or < 1 ppm → Dental cavities 
- Excess → Defects of bones, Dental floureness, Bones and joints stiffness 
- Nalgonda method → Highly adopted for fluoride removal 
8. Metals
- Non Toxic → Ca, K, Na, Fe, Mn, Zn 
- Toxic → Arsenic, Lead, Mercury, Cyanide, Cadmium, Chromium 
- Potassium thiocyanate is used to colour both the water sample & the standard solution for the determination of iron 
- Arsenic → Affects the lungs 
- Excess Sulphate → Laxative effect 
- Excess Lead → Anaemia 
- Sodium → Taste and odour problem 
- 1 ,10 Phenanthroline → Indicator for measuring iron concentration in water 
- Iron and manganese → Removed by aeration followed by coagulation, Iron can be removed by oxidation with chlorine 
9. Dissolved Gas
- CH4: explosive tendency 
- H2S → Bad taste & Odour, Basic cause of crown corrosion 
- C2O: water become corrosive & gives bad taste 
C. Biological Properties
- Coliform/Faecal coliform count in 100 ml of drinking water = 0 
- Coliforms → Bacteria coli (B-Coli), Escherichia Coli (E-Coli) & Entamoeba Histolytica harmless 
- Characteristics of coliform → Harmless, Bacillus, Gram-negative, Ferments lactose 
- Coliforms → Indicates the probable presence of pathogenic bacteria 
- Pathogenic bacteria enter wastewaters primary from domestic waste 
- Autotrophic Bacteria → Bacteria which use carbon dioxide as a source of carbon 
- Chemoheterotrophic Bacteria → Consume organic matter as a source of carbon and energy 
- Aerobic bacterias → Flourish in the presence of free oxygen, Consume organic matter as their food, Oxidise organic matter in sewage 
- Anaerobic bacterias → Sludge digestion 
- Facultative Anaerobic → Can survive with or without free oxygen 
- Agar of gelatine → The cultural medium used in finding the total count of bacteria 
Coliforms Test
i. Membrane filter techniques
- Nutrient 
- coliform colonies is counted 
ii. MPN test (Most Probable number)
- By multiple tube fermentation 
- Nutrient used: Lactose 
- Presumptive test, Confirmative test, Completed test. 
- Green lactose bile is used in presumptive tests. 
iii. Coliform index
- 15 test tube is used 
Natural Organic matter(NOM)
- NOM is Formed due to decay and leaching of organic detritus 
- NOM is found in particulate, colloidal and dissolved forms in all ground and surface waters, as well as in rainwater 
- NOM will have significant impacts on drinking water treatment processes aimed at protecting public health. 
Water borne disease
- Bacteria → Typhoid fever, Cholera, Bacillary dysentery, Tularemia 
- Protozoa → Amoebic dysentery 
- Virus → Jaundice, Poliomyelitis, infectious 
- Other → Gastroenteritis, Tinnitus 
Other disease
- Goitre → Lack of iodine 
TREATMENT OF WATER
- River water as property of self purification 
- Ground water containing Excessive iron, Dissolved CO2 & odorous gases 
- For construction use at a village site → the local pond water must be Sieved 
- Screening → Aeration → Coagulation and Flocculation(1st stage) → Sedimentation(2nd stage) → Filtration(3rd) → Disinfection/Chlorination(4th) → Softening → Defluoridation 
- Unit process in water treatment system → Softening, Coagulation, Adsorption 
- Surface water (river, canal) → coagulation, flocculation, sedimentation, filtration and disinfection 
- infiltration gallery → Aeration, coagulation, sedimentation and Disinfection 
- Lake/ Pond water → CuSo4 treatment, coagulation, sedimentation, filtration and disinfection 
- Tube well water → Disinfection 
- Iron and manganese → Aeration and sedimentation 
- The chemical energy content in an algae cell = 600o calories per gram of algae 
Activated Carbon
- Most commonly used adsorbent in water and wastewater treatment 
- Removes → Taste and Odours, Colour, Soluble organic Chemicals, Phenol type impurities, iron, manganese, Organic matter 
- As a Coagulant it accelerates the coagulation 
- Minimise chlorine demand 
- Overdose is not harmful 
Screening
- Area of opening should be such that→ that Vf = 0.75 - 1.0 m/s 
- inclined 3 - 6V : 1 H or 45° - 60° → Help in racking 
- Coarse & Fine Screen 
- IS 6280 → The screening units provided before the wet well 
Microstrainer
- useful for screening stored water 
- Plankton, Algae, other small size particle 
- wire mesh = 10mm size 
Pre-chlorination
- raw water not so turbid but high bacteria count 
- kills Algae, Bacteria and ↓es colour & slime formation 
- extremely polluted clear raw water 
Algae Control
- Best way is by Pre Chlorination 
- Remove → Alum 
- if org is more → Heavier dose of Copper Sulphate (2 mg/l) or Chlorine(3-5 ppm) 
Aeration
- Removes → Dissolved gases CO2, H2S, oil, Algae, Bad Odour, Undesirable gases, Excess iron 
- Generally used for Groundwater 
- remove Volatile liquid ex. Phenols & humic Acid 
- Remove or Converts iron & manganese Soluble to insoluble state → Dissolved iron is oxidised into forric hydroxide 
Disadvantage of Aeration
- Excessive Aeration absorb too much oxygen & water becomes Corrosive 
- ↑es Acidity of water, Excessive aeration may result into corrosion of metal 
- Needs Higher Capital cost, operating cost & maintenance cost 
- Sometimes it creates odour & nuisance 
Process of Aeration
- i. Spray nozzle → Remove 90% CO2 & 99% H2O 
- ii. Cascade method → Cheapest method 
- KMnO4 is used to help Oxidation 
COAGULATION
- Chemical + Water → Used to enlarge size of impurities → Reduces the net electrical repulsive force at particle surface 
- Remove → Colloidal impurities/solids, suspended 
- Jar test → To choose best coagulant, Optimal time required for flocculation, To find the chlorine content of water 
- Coagulant perform better in alkaline water 
- Went Turbidity > 40 ppm 
- Detention period = 2 - 6 hrs 
- Sweep coagulation → Raw water having high turbidity and high alkalinity 
- Vigorous mixing is done in a chamber where coagulant is added 
Types of Coagulant
- i. Alum or Aluminium sulphate (AL2(SO4)3.18H2O) → Best, cheap, most commonly used for water treatment, Function Better if Raw water is alkaline with high turbidity, pH range = 6.5 - 8.5, Increases acidity of water(↓es pH), Best for removing colour, taste, odour, colloidal particles 
- ii. Chlorinated Copper → Chlorine:Copper = 1:12.5, Work in large pH, Singularly effective in production sludge for the activated sludge process 
- iii. Copperas or Ferrous sulphate → 
- iv. Sodium Aluminate: Costlier coagulant 
- v. Iron Sulphate: Colour removal 
- vi. Ferric chloride → Widely used for sewage treatment, If about 90% of suspended solids are to be removed by coagulation 
- Na3PO4 → Highest power for coagulating positive colloids 
FLOCCULATION
- Flocculation agent is added to remove fine suspended particles → Gently mixing the water and coagulant allowing the formation of large particle of flocc 
- Slow mixing & agitation process 
- Most efficient Floc formⁿ → ↑es V gradient & ↓es time 
- Clarification → Process of adding chemicals to induce aggregation & Settling/Removing of finely divided suspended matter, colloidal substance etc 
- The efficiency of a clear clarifier → Depends on depth of the clarifier 
- Optimum time of flocculation = 30 minutes → Time increase beyond this the flocs will entrap air and will float in the sedimentation tank 
- Temporal mean velocity gradient → G = 20S-1 - 80S-1 
SEDIMENTATION
- To remove suspended solids → Process related to bed material carried by flowing water 
- essential factor = surface loading of tank 
- pH value of water doesn't affect Sedimentation 
- Discrete settling → free settling of particles 
- Backwash arrangement is made only in the case of a sedimentation tank 
- If the temperature of a sedimentation tank is increased → Sedimentation speed will get Hastened 
- Velocity of flow of water = 15 - 30 cm/min ( 2.5 - 5 mm/sec) 
- Depth of sedimentation tank ≤ 6 m 
- Displacement efficiency → Represents the short circulating occurring in a sediment tank 
- Critical shear stress ∝ Particle size 
Categories of Sedimentation
i. Plain sedimentation (Type-I)
- Due to Self weight of by action of natural forces alone 
- Generally rectangular shape tank is used 
- Surface overflow rate = 12k - 18k ltr/m²/day = 500-750 ltr/m²/hr 
- Detention period = 6 - 8 hrs → Time taken by a particle of water to pass between entry and exit 
ii. Sedimentation with coagulation (Type-II)
- Surface overflow rate = 24k - 30k ltr/m²/day = 1000 - 1250 ltr/m²/hr 
- Detention period = 2 - 4 hrs 
- Clariflocculator → Coagulation cum sedimentation unit 
Tank type
i. Quiescent type tank
- min = 3 → 2 Operational & 1 standby 
ii. Continuous flow Type
- Horizontal flow → Rectangular 
- Vertical Flow → Circular 
Rectangular tank
- (BxLxH) → L < 4B 
- Horizontal flow time → t = L/Vf = tank length/ flow Velocity 
- Flow velocity → Vf = Q/BH 
- Surface overflow rate → Vo = Q/BL = Discharge/surface Area 
- Overflow rate, surface overflow rate & Surface loading (Vo) → All are Same & it is the most imp design parameter → Vo Should we such so we can achieve settling velocity 
- Detention period → t = Vol/Q = Volume/Flow rate 
- Setting Velocity → Vs = L/t 
- Efficiency → η = h/H = Vs/Vo=Settling velocity/ Surface overflow rate 
- η ∝ 1/Vo ∝ As → Efficiency does not depend upon depth of the tank 
- For a given discharge efficiency of sedimentation tank can be increased by increasing the surface area of tank 
Setting Velocity Vs
- if Re < 1 & d ≤ 1mm 
- Stoke's Law → Vs = (γs-γw)d²/18μ =(G-1)γwd²/18μ → Laminar flow, μ = NS/m² & V = m/s, d = particle size 
- Settling velocity < Surface loading 
- Vs → Depends upon length of tank 
FILTRATION
- Process of purifying water by passing it through a bed of fine granular material 
- Removal of suspended impurities → Remove fine flocs, colour, dissolved mineral, microorganisms, Removes bacteria and colloidal solids 
- Economically effective in controlling Guinea worm disease 
- Rapid gravity filters → Remove bacteria and colloidal solids 
- Process: Bio-filtration 
- Best filter media send → D60/D10=02 
- Stone/Brick ballast → filter material used in contact bad 
- Double filtration → 1st filter is Pressure filter 
- Basic filtration mechanisms → Interception, inertia, Brownian diffusion 
- The void spaces in the filtering material act like a tiny setting basins 
- Well screen recruitment → Resistance to corrosion, incrustation and deterioration, Enough structural strength to prevent collapse, minimum resistance to flow of water into the well 
- Rate of demand = (Area x filtration rate)/(population). 
- Area of filter = Total water demand /filtration rate 
- Li(1-ni) = Le(1-ne) 
DISINFECTION
- Killing harmful organisms, Pathogens causing disease → Also for Colour, Odour, Algae 
- pH is control during disinfection to ensure that powerful residual Hypochlorous acid (HOCl) is formed 
- HOCl is most destructive, it is 80% more effective than OCl⁻ ion 
- Sterilisation Process: all organism (Harmful & non-Harmful) are killed by a physical phenomenon 
- Drinking Purpose: plain disinfection is sufficient → Most ideal disinfectant used for drinking water is chlorine 
- Swimming pool disinfection → Chlorine, Bromine, Ultraviolet rays 
- Potassium permanganate is not desirable for disinfecting drinking water because it imparts pink colour 
- In chlorination due to rise in temperature of water → Death rate of bacteria increases 
- Chick’s law → Nt=Noe-kt 
Methods of disinfection
- Physical method → By Boiling, By UV rays(turbidity < 15 ppm) 
- Chemical method → Oxidising agent (O3,I2,Cl, Br2), Metal ions (Ag, Cu), Alkalies & Acids 
- Minor method of Disinfection → Ozone Treatment, Treatment with excess lime, Treatment with F & Br, Treatment with KMnO4 
- Major method of Disinfection → Chlorination 
- Dechlorinating agents → Sulphur dioxide gas (SO2), Activated carbon, Sodium thiosulphate(NaHSO3), Sodium sulphite (Na2SO3) 
- Amount of potassium permanganate required for disinfection → 1 - 2 mg/L 
- O3 → Necessary residual Ozone can induce cancer 
- Disinfection Power → Ozone > HOCL > Monochloramine > NCl3 
Chlorination
- Generally used for Drinking water → Controls Schistosomiasis 
- Chlorine demand = Applied - Residual chlorine 
- Dosage of Cl2 = Demand of Cl2 + Residual Cl2 
- Fresh Bleaching powder = 30 - 35% Chlorine 
- HOCL is most Destructive 
- η ∝ Temp 
- [(HOCL)/(HOCL + OCL)] = 1 / 1 + K/[H+] 
- K = reactⁿ rate & H+ = moles/ltr 
- At lower pH contact period required for chlorination is low & vice-versa 
- Disinfection efficiency of chlorine is reduced → By increased PH value 
- Efficiency of disinfection by chlorine water treatment increase → by prechlorination 
- If Coagulation & Flocculation are poor then chlorine Demand will increase 
- Test of Chlorine Residue → DiSCO → DPD, Starch iodine, Chlorotex, Orthotolidine 
- The amount of residual chlorine left in public water supply for safety against pathogenic bacteria = 0.05 - 0.5 ppm 
Types of Chlorination
- Plain Chlorination → For clean water, Treatment of water with only chlorine 
- Pre Chlorination → Before coagulation and filtration, Reduce tastes and odour 
- Post Chlorination → After all the treatments of purification of water are completed 
- Double Chlorination → Pre + Post combinedly 
- Breakpoint Chlorination → in the stage when chlorination of water should be Stopped, Addition of chlorine in and amount sufficient to react with any Ammonia and readily oxidizable organic matter 
- Super Chlorination → Chlorination is done beyond breakpoint, During an epidemic 
- Dechlorination → Removing of residual chlorine 
PH values for Chloramine
- Mono chloramine > 7 
- Dichloramine = 4- 7 
- Trichloramine = 1 - 3 
SOFTENING
- Temporary hardness is removed by simple boiling 
- Lime is added to remove calcium hardness 
Permanent hardness removal methods
- Zeolite process is costlier than lime soda process 
i.Lime soda process
- Huge amount of precipitate form which creates Disposal problem 
- ↓es corrosion & ↑es Alkalinity 
- Lime reduces the carbonate hardness while soda reduces the non-carbonate hardness 
- Recarbonation → Conversation of precipitators to soluble forms in water 
ii.Base exchange process (Cation exchange process)
- Zeolite is a natural or synthetic Cation ex. Hydrated sodium aluminium silicate. 
- Costlier than LSP due to presence of iron & manganese 
- Zero hardness → By ion exchange treatment 
- Zeolite process: removal of calcium & magnesium cations 
- Most common artificial zeolite is Permutit 
iii.Demineralization Process
- Removes all minerals in water 
Treatment of Salinity of water
- Reverse osmosis and electrodialysis 
Reverse osmosis
- To remove dissolved solids 
DISTRIBUTION SYSTEM
- Water supply system means the complete Layout from the source of supply to the distribution system 
- Storage of water by impounding → Where Large variation in quantity of the river flow from time to time 
- Leakage losses are less when the water supply is intermittent → Pressure is less in intermittent Water supply 
- Maximum score depth for a severe band = 1.75R 
- Design period for water supply project = 20 - 30 years 
- Water losses in water supply is assumed = 15% 
- Cesspool → To collect foul and wastewater 
- Double stack system → To separate pipes for drainage of soil waste and wastewater 
Hazen-Williams formula
- Design of distribution system for water supply 
- Hazens Williams : Velocity of water supply 
- hf=(10.67LQ1.852)/(C1.852D4.87) 
- V=0.85CR0.63S0.54 → Water supply mains or Pipe flow 
- C = 99 - 100 → 20 year old C.I. Pipe 
Methods
- Gravitational system → From high level water resource 
- Direct Pumping → Low level resource or groundwater, Axial flow pump is used 
- Combined system → Elevated tank 
Layouts of distⁿ system
1. Dead end/Tree system
- Old town, randomly planned city, irregular grown town, Haphazard growth 
- Flow is unidirectional 
- Least number of cutoff valves 
2. Grid iron/Reticular/interlaced system
- Well planned city & town → Where the water mains and branches are laid in rectangles → Lateral are provided only one side of sub-main → Mains, sub mains and branches are interconnected 
- Cut off valves are provided at every junction 
Disadvantage
- Requires more length of pipelines and a greater number of cut-off valves 
- Its construction is costlier 
3. Ring/Circular system
- The supply main is laid all along the peripheral roads and sub mains branch out from the mains 
4. Radial system
- Very large area is divided into different zones the water is pumped into the distribution Reservoir kept in the middle of each zone 
- City with Roads radiating from centre 
- higher service head & efficient water distⁿ 
- water flows towards the outer periphery 
Types of pipe
- Life of cast iron pipes > life of wrought iron pipes 
- Sulphur bacteria causes the corrosion of iron and steel pipes embedded in soil 
- Concrete pipes → Jointed by Collar joint and Flush joint 
- Cast iron pipe → Pressure ≤ 7 kg/cm², Generally used in India for conveying water, Rising main, Spigot and socket joint is provided 
- Galvanised iron pipes → Coating of zinc, Water supply to residence or Within building 
- Gooseneck → A small sized bent/curved flexible pipe provided between ferrule and stop-cock, L = 75cm → To avoid stresses and strains on the joint due to temperature variation and vibrations 
- Ferrule → Installed in water distribution system 
- Minimum residual pressure at ferrule for one storey building = 7m, 2 storey = 12m, 3 storey = 17m 
- Working pressure of a class A pipe of increasing thickness for the same diameter = 1800 kN/m² 
- One pipe system → Commonly used in multistoried building 
Pipe test
- Air test → Underground & vertical pipe 
- Water test → Underground house sewer pipes 
- Smoke test → Rainwater pipe or Existing vertical sullage leakage 
- Food drainage pipes in building → smoke test 
Economical dia of pumping mains
- D = (.97 - 1.22)√Q, D = m & Q = m³/s 
- Valve closure time Max t = 2L/V. 
- Ht of the sink of the wash basin above floor level = 75 - 80 cm. 
Pipe Size → Design Condition
- D < 0.4m→ ½ full at max Q 
- 0.4 ≤ D ≤ 0.9m →⅔ full at max Q 
- D > 0.9m→ ¾ full at max Q 
- D = 40 cm → V > 1.8 m/sec 
Network Analysis
i. Hardy-cross method
- Most widely used for analysing and designing the pipes of all types of complex water distribution network 
- Σ Pressure drop = 0 around close loop 
- Σ inflow = Σ outflow 
- Head loss = rQⁿ. 
ii. Equivalent pipe method
- Sluice elbow pipe fitting as least frictional resistance in equivalent pipeline in terms of diameter of the pipe 
Valves
- Sluice or Gate or Shut off valves → Regulate the flow of pipe and overhead reservoir 
- Globe valve → Regulate the flow of after through the pipeline 
- Air valves or Air relief valve → To prevent air accumulation, Every summit of pipeline & d/s of sluice valve 
- Check/Reflux/Non-returning Valve → Works Automatically and Only one direction flow → Suctⁿ pipe, Tube wells, Pump 
- Scour/Blow off/Drain Valve → At Dead end or low point of pipe line, Drain off all accumulated water in pipes, Remove sand, silt .etc, Drain/Empty/dewatering the pipeline 
- Relief/Cut Off/Safety Valve → Regulate water hammer Pressure, Operates automatically when the pressure in the pipe exceeds the set pressure 
- Foot valve → Prevent entry debris & backflow 
- Ball/ball float Valve → Maintain constant level in reservoir & tank 
- Butterfly Valve → Large size conduit regulate & stop the flow 
- Pilot Valve → Reduce high inlet pressure to lower inlet pressure 
- Release Valve → Remove air from the pipeline 
- Pressure reducing valve is actuated by the fluid pressure at downstream 
SOLID WASTE MANAGEMENT
- Ministry of environment, forests and Climate change → Brings about the hazardous waste management and handling rules in India, Responsible for the overall monitoring of the implementation of the solid waste management rules 
- Jacobs Hochheiser method → Determine N02 
- Non disposal of solid waste may cause the spread of typhoid 
- Solid waste → Cow dung = 18 - 25 %, Night soil = 11 - 15% 
- Field capacity → Physical characteristics of municipal solid waste → Critical importance in determining the volume of leachate in landfills 
- Bulk density of MSW compost → Sample dried in a hot air oven at 70°C for 24 hours 
- With passes of time filled up solid waste will get stabilised by decomposition 
- Waste management hierarchy :– Prevention → Reuse → Recycle → Disposal 
Type of solid waste
- Municipal Solid Waste → Refuse, Trash, garbage, Institutional waste, demolition waste, Municipal service waste, Non hazardous waste 
- Industrial Waste → 
- Hazardous Waste → 
- Refuse → Dry or solid waste of society 
- Rubbish → Non-putrescible waste (inorganic) except ash 
- Garbage → Putrescible(सड़ने योग्य) organic waste, 0.2 - 0.4 kg per person, City = 450 gm per head per day 
- Bacillary dysentery: By garbage 70k fly 
- Solid waste generated per day per capita → Small city = 0.1kg, Medium city = 0.3-0.4kg, Large City = 0.5kg 
- Sullage/Dirty water → Waste water drained out from kitchen, bathroom, wash basin & floor washing 
- Sludge → Generic term for solid separated from suspension in a liquid → 20 litres per person per year 
- DWF → Dry weather flow 
Disposal of Solid waste or Refuse
- Chemical transformation of solid waste → Combustion, gasification, pyrolysis 
- Best process of disposal of batteries is recycling 
- Aerobic decomposition → CO2, NH3, H2S 
i. Open dumping
- Oldest & not an economical method, highly unacceptable 
- impact → 
ii. Sanitary land filling
- An engineered pit, in which layers of solid waste are filled compacted and convert for final disposal 
- Canyon Method → Landfilling of solid waste 
- Area method → Used in flat areas or gently sloping land, as well as in quarries, ravines, and pits 
- Trench method 
- Clay(bentonite) is used for landfill cover material → Control of gas and leachate movement 
- Rat & fly breeding 
- Can no longer be used for disposal of solid waste in India due to leachates 
- Leachate → The liquid that collects at the bottom of a sanitary landfill and may pollute the groundwater 
- Central pollution control board → Ambient air quality at the landfill site shall meet the standard → for Industrial Area 
- Post closure care of landfill site shall be conducted for at least 15 years 
- Land filling is not used for disposal of hospital waste 
- Bioreactor landfills → Moisture is the main factor for controlling microbial digestion 
iii.Composting
- Most acceptable economically and ecologically, Most hygienic → limited to special waste & selected material 
- Suitability → High moisture content, high organic materials, low calorific value, low inorganic materials 
- Bangalore method → Anaerobic method 
- indore method → Aerobic method, the entire process takes 04 months 
- Mechanical composting → Dano process, Buhler process, Tollemache process, Nusoil process 
- Window composting → Time required for decomposition = 2-6 months 
- Catalytic combustion → Used in purifying emissions from Industries like varnish, cooking and asphalt oxidation 
- For high rate composting → moisture content = 50 - 55% minimum 
- Maximum C/N = 30 → Municipal solid waste compost 
- Ideal Carbon to nitrogen ratio → C/N = 25 - 30 
- High C/N ratio → Correct by adding dehydrated mud 
iv. Pulverization
- Pulverised in a grinding machine to ↓es Vol 
v. Incineration
- Presence of air Burning in well designed furnace ex. Screen 
- High operation & maintenance cost 
- Indian Municipal solid waste is not suitable for incineration → Due to high moisture content 
vi. Pyrolysis or Destructive distillation
- It is an Irreversible chemical change 
- Thermal decomposition of waste in absence of air/oxygen → Oxidation at high temperature 540 - 1000℃ 
- Internal heating causes organic matter to decompose physically and chemically rather than burn 
- Plastic, rubber, leather 
- Pyrolysis is an Endothermic process 
- Most efficient method to conserve energy in the form of oil or gas 
WASTEWATER CHARACTERISTICS
- Harmful Bacteria in sewage → E-Coli, Salmonella 
- Pathogenic bacteria enter wastewaters primarily from domestic waste 
- Tolerance limit for industrial effluents discharged into public sewer → T < 45℃, pH = 5.5 - 9, BOD5 = 30 - 100 ppm 
- Specific gravity of sewage = 1.2 - 1.4 
- Deoxidation is caused by Organic matter in solution 
- Strength of sewage is given by concentration of organic matter 
Physical Characteristics
- Turbidity → Normally turbid 
- Colours → Fresh sewage is grey , as time passes it becomes black 
- Temperature → Sewage > Water 
Chemical Characteristics
- Dissolved solid : Reverse Osmosis, trickling filter 
- Colloidal solid: Coagulation 
- Volatile Solid: Digestion → muffle furnace 
- Settleable Solid: Sedimentation→ imhoff tank 
- pH → Potentiometer 
- For fresh sewage → pH = 7 - 14, usually = 8 
- Every daily per capita contribution of suspended solids = 90 grams 
- Fresh sewage → Alkaline, Septic sewage → Acidic 
DO → Dissolved oxygen
- DO ≥ 4ppm → Survival of organisms 
- By winkler's method 
- Measured by → Titrating water with (N/40)Na2S2O3 
- DO in sea water = 20% Less than stream/river water 
- Production of oxygen due to algae photosynthesis during daytime → Highly supersaturated with dissolved oxygen in water 
- Excess DO → Corrosion of pipe 
- Odour of hydrogen sulphide is emitted from domestic waste water when dissolved oxygen is absent 
- DO ∝ 1/Temp 
- DO → Maximum at noon in stream 
- DO winter > DO summer 
- Natural unpolluted water at normal temperature → DO = 10 mg/L 
DO Test
- A single Rapid test to determine the pollution status of river water 
- Manganese ions react with Hydroxide to form a precipitate of Mn(OH)2 
- Oxygen present → Brown precipitate, Oxygen not present → White precipitate is formed 
TOC → Total organic carbon
- Detect the total organic carbon of the sample → Reflects the organic contamination 
COD → Chemical oxygen demand
- COD represents Strength of sewage 
- meas content of organic matter of waste water Both biodegradable & Non - biodegradable → Amount of oxygen consumed by sewage from an oxidising agent like potassium dichromate 
- Potential Dichromate taste in presence of Sulfuric acid 
- TOD ≥ COD ≥ BOD ≥ TOC 
- ideal conditions → COD/TOC = 2.66 
- Typical untreated domestic wastewater → BOD/COD = 0.40 - 0.80 → COD/BOD > 1 
- High COD/BOD ratio → Low biodegradability of the pollutant 
Chemical oxygen demand test
- 95% organic matter is oxidised & results are available within 3 hrs. 
- Titrated with standard ferrous Ammonium Sulphate → To determine the unreacted amount of mercuric sulphate 
- Organic matter is oxidised by potassium dichromate (K2Cr2O7) in the presence of sulphuric acid (H2SO4) 
- Indicator → Ferroin 
- COD test is relatively quick process then BOD test 
BOD → Biochemical oxygen demand
- BOD is the amount of oxygen required for biological decomposition of dissolved organic solids under aerobic conditions for 5 days at 20 degrees celsius 
- For biodegradable Organic matters only 
- The amount of organic material remaining at any time(t) is governed by first order function 
- 5day at 20°C is taken as Standard → Which is 68% of total/ultimate demand 
- Strong sewage → BOD5 = 450 - 550 
- BOD5 = (DOi- DOf) x DF → @20°C 
- BOD5 days = 0.68BODultimate=2/3 of BODultimate → @20°C 
- BOD520°C= BOD3 27°C , BOD5,32°C>BOD5,20°C 
- BOD10 days = 0.90BODultimate 
- KT=K201.047T-20 
- BOD5,T=Lo(1-e-KTt) → Lo=BODultimate 
- K → Increases with temperature if T > 20, Decreases with temperature if T < 20 
- BODultimate → Not affected by temperature 
- Average daily per capita contribution of BOD5 = 45 grams and BOD = 50 - 70 gm/day 
- Safe drinking water BOD = 0 
- Discharging sewage and industrial equipments into stream →BOD520°C<30 mg/L 
- Tolerance limit in public sewer → BOD520°C=350 mg/L 
- Deoxygenation: Exertion of BOD by microorganisms 
- If any Biodegradable organic material is present in Wastewater → BOD = 0 
- Effluent from secondary biological treatment of sewage → BOD = 5 - 10% of the original 
- BOD Removal efficiency during primary treatment under normal conditions = 30% 
- BOD → Industrial water > river water > tap water > bottled water 
BOD Curve
- Stage 1 → Carbonaceous demand 
- Stage 2 → Nitrogenous demand 
- Lt = Organic matter at present 
- Biomass curve :– Lag phase → Log → Growth phase → Stationary phase → Endogenous phase 
Dilution Factor
- DF = Vol diluted sample/Undiluted sewage sample 
- DF = Vs + Vw / Vs → Vs = sewage, Vw = water 
- if Dilution = 5% → DF = 100/5 
- DF > 500 → No treatment required 
- DF = 300-500 → plain sedimentation 
- DF = 150-300 → secondary treatment 
- DF < 150 → all treatment required 
- DF = 100 → Extensive treatment to bring BOD below 20 PPM and suspended solid (SS) below 30 PPM 
Population Equivalent
- Use to compare pollution potential sewage 
- Avg std domestic sewage → BOD = 80 gms per person per day 
- PE = Total demand of BOD of a city per day / individual BOD produced by a person per day = Total/80 
Relative Stability
- RS = (Available oxygen/Required oxygen)100 → Satisfying the first biochemical oxygen demand 
- RS = (BOD removed / Total BOD) 100 
Oxygen sag
- The difference between saturated dissolved oxygen content and the actual dissolved oxygen content in the stream at any point during self purification process 
SEWAGE TREATMENT
- Neutralization of alkaline effluent → Carbon dioxide treatment, using waste boiler flue gas, sulphuric acid treatment 
- Sewage treatment plant/units are normally design for 30 - 40 years 
- Dewater raw sludge → Filtering, Drying using flatbed, Centrifugal action 
- The treated sewage effluents are generally → Used for irrigation crops 
- Grab sample → Relatively employed for the design of wastewater treatment plants 
- Centrifuge → A device in which sludge is dewater by rapid rotation and automatically discharged 
- Aqua privy → Most economical and hygienic privy for rural areas 
- Deplorable aspect of conservancy → Human element is involved in collection and transportation of human waste 
- Water carried sewage system is better than the old convergence system 
- Sludge bulking → Sludge with poor setting characteristics → Can be controlled by Chlorination 
- Oxidation is Essential → for the biochemical treatment of sewage effluents 
- Nitrogen is present in wastewater sample due to the decomposition of proteins 
- Raw domestic sewage mostly contains Nitrogen in form of → organic-N and ammonia-N 
- Allowable disposable rate of application of sludge on land is determined by → Nitrogen content of sludge 
- The very first stage decomposition of organic matter in sewage → Ammonia is formed 
- A well oxidised sewage contains nitrogen mainly as nitrates 
- Nitrate detection in sewage → Colour developed by adding phenol-di-sulphuric acid and potassium hydroxide 
- Dilution → To maintain the aerobic condition of sewage, the sewage is mixed with a large quantity of water 
- Crude sewage → Sewage that has received no purification treatment 
Sewage sickness
- Phenomenon by virtual which soil pores gets clogged with sewage matter, due to excessive application of sewage to land, obstructing aeration and leading to septic condition 
- Prevent → Rotation of crop, Pretreatment of Sewage, Shallow depth application 
Treatment Methods
- Sludge treatment → Stabilise the organic matter, Destroy the pathogenic bacteria, Reduce the water content 
- Unit Operations → Physical forces are predominant e.x. Sedimentation, screening, mixing .etc 
- Unit Process → Addtⁿ of chemicals, biological mass or microbial activities ex. ASP, Trickling filter, Oxidation Pond 
- Primary Treatment → Screening, Great chamber, Skimming tank 
- Secondary Treatment → Trickling filters, Contact beds, Sand filters 
- Screening → Grit chamber → Primary sedimentation → Aeration → Secondary sedimentation 
- Conventional sewage treatment → Grit chamber is placed ahead of the trickling filter 
- CETP → Common effluent treatment plant 
- Clariflocculator → Floc formation & its subsequent removal by Sedimentation 
- Algae-bacteria symbiosis is observed in stabilisation pond 
- Sewage treatment units are designed for → Average flow only 
- Decomposition of sewage takes place causing a pungent smell of H2S 
- Equalisation basin → To absorb fluctuation of flow rate, Damping the hourly variation in the sewage flow 
PRIMARY TREATMENT
- BOD removal efficiency under normal condition = 30% 
Screening
- Floating material, Large size stones and gravels 
- To protect Pumps & other mechanical equipment 
- Head loss h = 0.0729(V² - v²) = k(V² - u²)/2g 
- h ≥ 50% → The Cleaning is Required 
- Micro screening → Removal of algae from stabilisation pond effluents 
- Spacing of Steel bars in coarse screen = 50mm 
Grit Chamber
- To remove suspended inorganic grit like sand gravel & any other mineral matter with a nominal size of 0.15 - 0.20mm 
- Removes particles of size ≥ 0.2mm, Gs ≈ 2.65, Dt = 30 - 60 sec & Depth = 1 - 1.5m 
- for 0.2mm particle Settling V = 0.025 m/s 
- Grit chambers are usually changed after 2 weeks 
- Horizontal critical flow Velocity → Vc = Kc√(g(GS - 1)d) ← Critical Scour Velocity, Kc = 3 - 4.5 
- Proportional flow weir (Parshall flume) → To maintain constant flow velocity in the grit chamber over a certain depth range 
- Detritus tank → Removal of fine sand particles and grit 
Skimming Tank
- Removal of Soap, oil, Grease, Fat .etc 
- A = 0.00622q/Vr 
- Rate of flow q → m³/day 
Settling tanks
- in primary settling tanks the suspended solids are reduced to 40 - 70% 
- Secondary settling tanks are designed to remove bio flocculated solids 
SECONDARY TREATMENT
- Attached + Aerobic biological →Trickling filter & RBC → Conversion of suspended organic matter into settleable biofloc and stable inorganics 
- Suspended Aerobic → Activated sludge Process & Oxidation/Stabilisation pond 
- Suspended Anaerobic → Septic tank & UASB Reactor 
- Imhoff Tank → Suspended Anaerobic (Lower part) & Suspended Aerobic (Upper part) 
- Bulking of sludge can be controlled by chlorination 
- Max efficiency of BOD removal → oxidation ditch 
- Largest land area for a given discharge will be needed for oxidation pond 
Activated sludge process
- Biological process → Aerobic bacteria + Protozoa + algae 
- Oxidation ditch → A modified activated sludge process 
- Activated sludge → Contents fertilising constituents, indicates the degree of aeration, indicates high water content 
- Dominating micro organisms are → Aerobic heterotrophs 
- Rising sludge occurs due to → Denitrification in the settling tank 
- Bacteria are removed = 80 - 95%, BOD removal eff = 95% 
- BOD of secondary effluent < 30 mg/L 
- Indian Condition → SVI = 150 - 350, Good sludge →SVI = 50 - 100 ml/gm 
- Sludge vol index → SVI = (Sludge vol / Suspended solid wt)x1000 
- SVI use → Indicate physical state of the sludge produced, Decide recirculation ratio of sludge 
- F/M = QoSo/VX= BOD load / microbial mass = food added / Bacteria in system 
- Lower F/M ratio → Higher BOD removal 
- Conventional activated sludge treatment plant → The return sludge is added at entrance of the aeration tank, F/M = 0.3 - 0.4 
- Mixed liquor → The combination of liquid and microorganism undergoing aeration 
- Removal of soluble organic Chemicals is possible by the addition of activated carbon to the biological mixed liquor of an active sludge process 
- Recirculation → To supply seed materials to the aeration tank 
Trickling filter
- Biological oxidation process to remove → Dissolved and Colloidal organic matter, BOD 
- Surface area for growth of biofilm is provided by randomly packed solid forms 
- Inherent problems of Odour, Ponding and fly nuisance 
- η = η1 + (1 - η1) η2 
- Design parameters → Hydraulic loading rate(m³/m²/day), Organic loading rate (kg/m³/day), Depth 
- TF Sizing criteria is based on hydraulic loading 
- Hydraulic loading rate of high rate trickling filter including Re-circulation = 10 - 40 m³/m²/day 
- Distributing arms of large trickling filter units are rotated at speed of 1/3 - 1/2 RPM 
- Work on Aerobic Decomposition of organic matter 
- Hydraulic Recirculation ratio = 1 + R, R = Circulation ratio 
- High rate trickling filter → Hydraulic loading rate = 10 - 30 m³/m²/day 
- Low rate trickling filter → Recirculation factor = 1 
- Unit organic loading → u = W/VF 
- Vacuum filters → Dewatering of sludge 
- Sloughing → Phenomenon of losing the Slime layer 
- BOD removal efficiency = 85%, BOD5 = 70 - 80% 
- BOD after the filtration of sewage from the low rate trickling filter = 80 - 90% 
- Problem of ponding can be solved by Raking and chlorination 
RBC → Rotating Biological contactor
UASB → Upflow anaerobic Sludge blanket
- Does not require any special media to keep sludge in suspension during treatment 
Oxidation/Stabilisation Pond/lagoons
- Anaerobic stabilisation → Gases CO2, CH4, Nitrate 
- Primary settling time is not required in some case, BOD removal occurs in two stage, Aeration volume requirements are approximately 50% of those of conventional or tapered aeration plant 
- Design factor → Surface area, depth and shape, inlets and outlets 
- Area → Based on 2000 persons to one acre of pond area 
- Sodium nitrate → Used to stimulate the algae growth when it gets overloaded 
- Biological waste treatment is governed → By bacterial degradation and Algal-bacterial symbiosis → The growth of algae is useful in oxidation pond 
- BOD and coliform removal is up to 99% 
- Types → Aerobic, Anaerobic, facultative 
- The process of lagooning is primarily a means of disposal of sludge 
- Mechanically aerated lagoons → Less detention time and areas are required, because these ponds are deeper than the oxidation ponds 
Oxidation ditch
- Excess sludge is taken to drying digester 
Sludge Digestion
- ↓es Vol of sludge & Render remaining solids and relatively pathogens free 
- Use both Aerobic & Anaerobic mechanism 
- pH = 6.5 - 8.0 → Alkaline condition should prevail 
- As a result of sludge digestion combustion gas → Marsh gas is generated → Methane(CH4) 
- Stages :– Acid fermentatⁿ → Acid Regression → Alkaline fermentatⁿ 
- Digestion step :– Hydrolysis→ Acidogenesis → methanogenesis 
- X(100 - P1) = Y (100- P2) → P1, P2 Moisture content corresponding to sludge quantity X and Y 
- i. Aerobic digestion 
- ii. Anaerobic digestion → Methane > CO2 formed, Acid formed, Reduces odour/flies problem, low operating cost, Total solid destroyed = 40-60%, Necessary to maintain proper pH 
- Moisture content reduced from 90% to 80% → 50% decrease in the volume of sludge 
- Sludge drying → To separate water from digested sludge or dewatering sludge 
Septic tank
- A Watertight chamber made of concrete, fibreglass, PVC or plastic, through which domestic waste water, sewage flows for primary treatment 
- Anaerobic method of onsite sewage treatment → Both Sedimentation + Digestion process → Settling + Digestion tank 
- Ideal for a small Colony, Rural area → Design as ordinary settling tank 
- Gases → CO2, H2, S, CH4 
- Decomposition of organic Bacteria is done by anaerobic bacteria 
- Rate of accumulation of sludge = 30 ltr/person/year 
- Sludge should be removed in 1 - 3 years 
- Desirable self cleaning velocity = 0.5 m/sec 
- Brick wall in cement > 20 cm 
- Capacity = 0.1 m³ per user → 25 users = 2.5m³ 
- Detention time = 12-36 hrs, L/B = 2 - 3, Connecting pipe ≥ 50mm 
- Soak/Seepage Pit → Circular covered pit through which the effluent is allowed to be soaked into the surrounding soil 
- Soak pit dia ≥ 3.0 - 5 feet 
Imhoff Tank
- Both Sedimentation + Digestion process of sludge takes place simultaneously 
- Settleable solids 
- Upper compartment → Aerobic 
- Lower compartment → Anaerobic 
SEWERAGE SYSTEM
- Sewerage → The process of collecting, treating and disposing of the sewage 
- Clamshell → Removing material from cofferdam, sewer manholes and well Foundation 
- Concrete sewer corrosion → Due to septic condⁿ & Anaerobic decomposition of sewage (Hydrogen sulphide) 
- Well oxidised sewage content sulphur largely in the form of sulphate 
- Maximum scour depth at a severe band = 1.75D 
- Storm sewage → Quantity of liquid waste which flows in sewers during the period of rainfall 
- Flushing tank → Located at sewer line with steep gradient 
- Axial flow screw pumps are mostly used in sewage pumping area 
- Nomograms → For ease in the design of sewers 
- During sewer cleaning the worker are exposed to hazards primarily due to presence of Methane 
- important factor for design of wastewater disposal → record of population and its change, water consumption rate and sewage flow, hydrological data 
Properties
- Sewer → The underground pipeline to dispose waste water produced by public 
- Gases in sewer → H2S, CO2, CH4 
- Sewage → 99.90% water + 0.1% Solids → Any wastewater of domestic or industrial origin 
- Max sewage flow → Q = q[(4+√P)/(15 + √P)] → P = population, q = avg sewage flow 
- Capacity of sewage pipe Q ∝ √S, S = bad Slope. 
- Supply reaches to sewer = 70-80% water 
- Sewer Dia = 100mm(L ≤ 6m) & = 150mm(L > 6m) 
- Minimum diameter for public sewer in hilly areas where steep slopes are prevalent = 100 mm 
- Velocity running full = V runing half 
- The minimum velocity at initial peak flow and ultimate peak flow in sewer ≥ 0.6m/s and 0.8m/s 
- Sewer must be off adequate size to avoid overflow 
- Flowing under Gravity 1/2 to 3/4th full 
- Sewerage system is usually designed for 25 years 
- Laying of sewers is usually done with the help of Sight rails and boning rods 
- Laid at least 2m - 3m deep to collect water from basements 
- Sewer should not be design to run full → To facilitate ventilation of sewer 
- Sewer are generally laid starting from their out fall point 
- Flow velocity in sewers does not depend on its length 
- Peak infiltration flow curves → Curve A = old sewers 
Sewer pipes
- Properties→ Heavy wt, highly impervious, High resistance to sulphide corrosion, High compressive strength 
- Test → Water test, mirror test, ball test 
- Sewer pipes have to be designed and checked for both maximum and minimum flow 
- Sewer pipes are made of stoneware → In stoneware pipe glazing is made for waterproofing 
- Lead sewer → Resists sulphide corrosion 
- Best sewer material to resist hydrogen sulphide corrosion → Glazed stoneware 
- Corrosion in concrete sewer is caused by H2S → Crown corrosion in sewer caused by sulphate 
Types of sewer
- Circular shaped sewer → Mostly used for all type of sewer, most commonly used under culvert 
- Oval/Egg-Shaped sewer → For combined & provide self cleansing velocity at low Q, Suitable for Varying Discharge 
- New-Egg-Shaped sewer → Overall depth = 1.625D 
- V-shaped with Circular → Best sewer section for dry weather flow 
- Common sewer → Shared more than one house 
- House sewer → Pipe carrying water waste from a building to the immediate point of its disposal 
- Branch → From the first element of a wastewater collection system or from one or more building to main or Trunk sewer 
- Lateral sewer → Receives Q of a number of house sewers 
- Main sewer → From one or more lateral sewers to trunk sewers or intercepting sewers 
- Trunk sewer → They are large in size, Discharge from two or more main sewers to waste water treatment plant or to intercept sewer 
- Outfall sewer → Collects sewage from the collecting systems and transport the sewage to the point of treatment or final discharge or to disposal plant 
- Interceptor sewer → From number of transverse sewers or outlets 
- Corrosion of concrete sewer occurs due to anaerobic decomposition of sewage solid 
Combined sewerage system
- Sanitary/domestic sewage + Surface(Strom) water → Dry weather flow + Rain water 
- Egg shaped Sewer are Preferred → Best shape of sewer considering the hydraulic properties 
- Cost of Construction & Pumping is high 
- More suitable for narrow streets 
- Less intensity of rainfall → Rainfall is distributed throughout the year such that it is ≤ 10 x DWF 
Storm/Surface sewer
- Time of concentration is relevant to determine the rainfall intensity 
Sanitary sewer
- Expected to run full 
Self cleaning
- Self cleansing velocity is velocity at which no accumulation remains in the drain → Achieved by providing adequate discharge, gradient through sewer lines → Neither sitting nor scouring occur at the bottom 
- Sewer is usually designed to attain self cleansing velocity at the minimum hourly flow rate 
- Vs = √[8KgD(G-1) / f] 
- Vs ∝ D(particle size) 
- All Sewer in india → Vs = 1.0 - 1.2 m/s 
- Self cleaning velocity recommended for Indian conditions = 0.75 m/s 
- Non scouring velocity for cement concrete sewer = 2.5 - 3.0 m/s 
- Self cleansing velocity should be maintained at least once in a Day = 0.45m/s 
- The minimum velocity of flow in a sewer should be ideally equal to self cleansing velocity 
- Gradient required to generate self cleansing velocity → Sewer dia = 150 mm → 1 in 100, 225 mm → 1 in 180, 300 mm → 1 in 220 
- Aerodynamic diameter is the diameter of a sphere of unit density(1g/cc) that has the same terminal setting velocity 
Note
- 1. max hourly Q = 3 x Avg daily Q 
- 2. max daily Q = 2 x avg daily Q 
- 3. min hourly Q = ⅓ of avg daily Q 
- Sewers must be checked for minimum velocities at their minimum hourly flows i.e. is ⅓ of Qavg. 
- The velocity of exit waste gases should be a min of 5/2 of wind speed to prevent downdraught 
Joints
- Mechanical joint → Used in metallic sewer 
TRAP
- Used to prevent entry of foul gases in the house 
- Their are 03 kinds of trap → P, Q & S trap 
- indian Type → 450, 300, 500mm 
- P-Trap used for an Indian Water closet 
- Height of the Sink of the Wash basin above floor level is kept 75 cm - 80 cm. 
- Gully trap → Collect wash water from floors, washbasins, kitchens and bathrooms → At the junction of unfoul Roof or room drain and a foul bath or kitchen drain 
- Anti-Siphonage Pipe → Connected to top of P-trap W.C. → To preserve the water seal of straps → Siphonage action occurs due to sewage discharge from the upper floor 
- Sewer trap → Provided at the last manhole connection of building drainage line to corporation main drainage line 
- intercepting traps → Provided to disconnect the house drain from the street sewer → At junction of a house and a municipal sewer 
- Floor or Nahani trap → Wastewater from floors of bath & kitchen. 
- Waste water pipe → Q from sanitary fittings like kitchens, wash basin, bathrooms etc. → But not human excreta 
- Vent Pipe → For ventilation purpose, exit foul gas in Atm. 
- Soil Pipe → Human excreta from water closet to septic tank 
- Two pipe system in building → One soil pipe + one waste pipe + two vent pipe 
- Water Seals → Provided to prevent foul gases 
- Cowl → Ventilating pipe, Provided on the top of soil pipe to prevent birds from entering and nesting in it 
Sewer Appurtenances
- Manholes, Drop Manholes, Lamp holes, Clean outs, Catch basins, Flushing Tanks. 
1. Manholes
- Means of access for inspection + Cleaning of sewer lines + Removal of part of sewer + Providing air for oxidation 
- Dia of opening ≥ 50 cm 
- Candle is lowered → To check presence of oxygen 
- Manhole covers are made circular to prevent falling of the cover into the manhole 
- Should be provided at → Every change of Gradient, alignment, diameter & direction, head of all sewer & branch, every bend, every junction, every 30m intervals 
- Max spacing of manhole in sewers up to dia ≤ 0.3m → 45 m, ≤ 0.6m → 75m, ≤ 5m → 250mm, > 5m → 300 mm 
Component of Manholes
- Access shaft → 
- Working chamber → Rectangular chamber size = 1.2 x 1.5 m, Circular chamber dia = 1.2m, ht ≥ 1.8m 
Types
- i) Drop manhole → Sloping ground, with drop > 0.6m required to control the Gradient, To connect high level branch with low level branch sewer, Change in elevation of Ground level, Hilly township 
- ii. junctⁿ manhole, 
- iii. Flushing manhole → Located at the head of the sewer 
- iv. Straight-Through manhole 
2.Lamp Holes:
- for Lowering a lamp inside 
3. Catch Basin:
- carrying Drainage Q 
4.inverted Syphon
- Inverted syphons are provided for taking sewer line below Road/Canal/Railway line 
5. inlets :
- Not provided in every sewer, storm water inlets have vertical openings 
DISPOSAL OF WASTE WATER
- Self purification of natural stream → Due to dilution, turbulence of water, oxidation-reduction, Sedimentation 
- Higher temperature, Sunlight, Satisfying oxygen demand → increases the self purification of stream 
- Hazen and camp → First develop the commonly used mathematical model relating the BOD exertion and Recreation to DO deficit in a stream 
- Rate of deoxygenation → LD= -KLOe-kt 
Zone of Pollution In River System
- Zones formed in a polluted river under the self purification process 
- Sag in curve → DO is a function of the rate of both addition and depletion of oxygen from the stream, Maximum DO deficit 
1. Z of Degradation
- Algae die but fish survived 
- DO falls to 40% of saturation 
2.Zone of Active Decomposition
- Heavy pollution & gases 
- DO even fall to Zero 
3.Recovery
- DO rises above 40% 
4.Clear water
- DO rise to saturation 
- Pathogens may remain 
AIR POLLUTION
- RSPM → Respirable suspended particulate matter 
- The Air Act 1981 → Prevention & Control of Pollution 
- Due to incomplete combustion of fuels from petrol engine → Carbon monoxide 
- Fabric filters → Air cleaning device which removes smallest particles 
- Mixing ratio = No. density of gas/No. density of all gases in dry air 
- Aerosols → Finely divided liquid droplets or solid particle capable of remaining suspended in air 
- The intensity of air pollution is found to be highest during winter 
- During temperature inversion in atmosphere air pollutants tends to accumulate below inversion layer 
Primary Air pollutants (SCN)
- 1. Organic compounds 
- 2. Oxides of Sulphur 
- 3. Oxides of Carbon, CO, CO2 
- 4. Halogen compound 
- 5. Oxides of Nitrogen 
- 6. Radioactive compound 
- 7. Particulate matter & Suspended Particulate matter 
- 8. Hydrocarbon 
Secondary pollutants
- Ozone (O3) 
- Formaldehyde 
- PAN ( peroxyacetyl nitrate), PBN, PPN 
- Sulphuric Acid (H2So4) 
- Smog = Smoke + Fog 
- Photochemical smog = NO + Hydrocarbon/oxidant + Sunlight → PAN 
- Nitrogen oxide is the major pollutant present in photochemical smog. 
- Natural Contamination of Air → Pollen Grains 
Source
- Photochemical reaction → O3 and PAN 
- Air pollutants which are monitored for petrol driven vehicles → NOx, PM 
- Thermal power plants mostly produce SO2 
- Major source of carbon monoxide pollution is automobiles 
Effect
- SO2 and → Affect functioning of the respiratory system 
- CO → oxygen carrying capacity of blood respect, impacts hearth, Combines with haemoglobin in blood 
- Sulphur dioxide (SO2) is harmful for plants 
Automobile exhaust:
- carbon monoxide, nitrogen oxides, hydrocarbon, sulphur dioxide, lead, particulate dust. 
Acid rain
- Sulphur oxides (SOx) & nitrogen oxides (NOx) interact with vapour & sunlight & are converted into strong Acids H2SO4, HNO3. 
- pH < 5 (4.5) 
Global warming
- Temp ↑es 
- Greenhouse gases → CO2(57%) , CFC(25%), CH4 (12%), Nitrous oxide N2O(6%) & fluorinated gases. 
Ozone(O3) layer Depletion
- Due to HCFC, methyl bromide , CFC or freons, Halons, HCL, Carbon tetrachloride, methyl chloroform. 
- Vienna convention (1985), Montreal protocol (1987) 
- Ozone occur in Troposphere 
- Protect us from UV rays 
- Effect → Skin cancer, Irritation of the eyes 
Air Pollution Controlling Devices
1. Forced field settlers
i. Gravitational settling chamber
- Large size particle D > 50μm 
- Removes Abrasive Particles from Gas Streams 
ii. Cyclonic or Centrifugal separator
- To remove → SPM 
- D > 10 μm (10 - 100μm) 
- Centrifugal force generated by the spinning gas, the solid particles are thrown to the wall of cyclone 
iii. Electrostatic Precipitators (ESP)
- D < 1μm 
- Most efficient = 95-99% 
- Uses electrical forces, Particles are removed by rapping & collected in a hopper. 
- Used in: thermal power plant, mining, industries 
2. Cotton bag house filter
- all sizes 
Dispersion of air pollutants in Atmosphere
- Lapse Rate → ↓es Temp as ↑es Altitude 
- 1. ELR = 6.5°C/Km ← environment/Ambient lapse rate 
- change in temp with ht in environment 
- 2. ALR = 9.8°C/Km ← Dry adiabatic lapse rate 
- Super adiabatic lapse rate: ELR > ALR → Unstable EVS 
- Neutral : ELR = ALR 
- Sub-adiabatic: ALR > ELR, Stable EVS. 
- Negative lapse rate & inversion: ↑es Temp as ↑es Altitude. 
Plume Behaviour:
- Path taken by Continuous Discharge of gaseous effluent from stack/chimney 
- 1. Looping plume: occurs in super adiabatic lapse rate (SALR), eddies are generated 
- 2. Neutral plume: ELR = ALR, Upward vertical rise. 
- 3. Fanning plume: under extreme inversion conditions, Plume farms out in horizontal directⁿ 
- 4.Coning plume: Cloudy day or night & Strong wind velocity (V ≥ 32 km/hr) 
- 5.Lofting plume: most favourable plume type 
- 6. Fumigation plume: Bad case of atmosphere dispersion, Bhopal Gas tragedy 
- 7. Trapping plume: neither go up nor down, 
Chimney
- Only two main forces are considered on the chimney one due to pressure and other due to self weight of the chimney 
- For stress calculations or analysis of forces on a chimney , the wind pressure is assumed to act on the Projected area of the chimney 
- Direct stresses → due to self weight of the chimney 
- Bending stress → due to Wind pressure on the chimney 
Stack/Chimney ht Design
i. Emitting SO2
- H = 14 Q^⅓ , 
- H = m & Q = kg/hr SO2 emission 
ii. Emitting particulate matter
- h = 74 Q ^0.27 
- h = m & Q = tonnes/hr 
NOISE POLLUTION
Units of Noise Pollution
- Decibels (dB) 
- Watt/m^2 
- Bels 
- Pascal 
For easy calculation
- Log10(0) = 0 
- 1,2,....9 = b/w 0 - 1 
- Log10(10) = 1 
- 11, 12,...99 = b/w 1 - 2 
- Log10(100) = 2 
Sound Pressure level
- Lp = 20 x log10(Prms/20 μPa) =10 x log10(Prms/20 μPa)^2. 
- 20 μPa = 20 micro Pascal = 20 x 10^-6 Pascal. 
Two Source L1 & L2 ( L1 > L2)
- Diff L1 - L2 & Resultant 
- 0 - 1 → L1 + 3 
- 1 - 3 → L1 + 2 
- 4 - 8 → L1 + 1 
- ≥ 9 → L1 
Source of equal noise level
- 2 → increase by 3dB 
- 3 → ↑es by 4.7 
- 4 → ↑es by 6 
- 5 → ↑es by 6.99 
Domestic noise → operation of radio, television, record players, etc.
Permissible noise level standards(dB)
- Banks/offices = 50-60 db 
Noise reduction due to the construction of Barrier wall
- Noise reduction(dB) = 10log10(20H^2 /λR) 
- R = Distance b/w source and wall 
- H = Height of barrier wall 
- λ = Wavelength of sound 
 

No comments:
Post a Comment